Would this be possible if the soloist track is already in use?
No. Sforzando is difficult to work with then it comes to changing sounds because it only loads a single instrument at a time and BIAB requires everything to be set up before the song is generated.
The sort of thing that you are trying to do is much more easily accomplished in Realband rather than BIAB. Realband has up to 48 tracks. Using these it would be possible to have two instances of the melody, each with different sounds, and to weave in and out of the two tracks to get the sounds you want.
It would also be possible to accomplish the same in a DAW. Just save two instances of the melody - one with one sound, one with another - and then use volume envelopes to move between the the two melodies.
The last option is to forgo using Sforzando for the moment and just use Coyote WT rather than HiQ sounds. With Coyote WT, what I wrote in the first post will work.
Hope this helps.
Regards,
Noel